Product ID:47652 EPA 552.1 ACIDS CALIBRATION MIX, 1X1ML
MSDS Date:07/25/1994
FSC:6550
NIIN:00F041316
MSDS Number: BXNMG

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

2-BROMOPROPANOIC ACID

CAS: 598-72-1

Fraction By Weight: 0.01%

BROMOCHLOROACETIC ACID

CAS: 5589-96-8

Fraction By Weight: 0.02%

2,2-DICHLOROPROPIONIC ACID; DALAPON

CAS: 75-99-0

RTECS: UF0690000

Fraction By Weight: 0.02%

ACGIH TLV: 5.8 MG/CUM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL TERT BUTYL ETHER (MTBE), 2-METHOXY-2-METHYL PROPANE

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 99-100%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CHLOROACETIC ACID CRYSTALLINE

CAS: 79-11-8

RTECS: AF8575000

Fraction By Weight: 0.03%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

DICHLOROACETIC ACID

CAS: 79-43-6

RTECS: AG6125000

Fraction By Weight: 0.03%

BROMOACETIC ACID

CAS: 79-08-3

Fraction By Weight: 0.02%

TRICHLOROACETIC ACID

CAS: 76-03-9

RTECS: AJ7875000

Fraction By Weight: 0.01%

ACGIH TLV: 6.7 MG/CUM

DIBROMOACETIC ACID

CAS: 631-64-1

Fraction By Weight: 0.01%

LD50 LC50 Mixture:ORAL LD50(RAT): 4000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: BURNS SEVERELY. SKIN: ABSORBED
RAPIDLY. BURNS SEVERELY. MAY BE FATAL IF ABSORBED. IRRITATION.
INHALATION: MAY BE FATAL AS A RESULT OF SPASM, INFLAMMATION & EDEMA
OF THE LARYNX & BRONCHI, CHEMICA L PNEUMONITIS & PULMONARY EDEMA.
IRRITATES NOSE & THROAT. CAUSES SEVERE RESPIRATORY BURNS.
LIVER/KIDNEY DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:BURNS, IRRITATION, BREATHING DIFFICULTY,
HEADACHE, NAUSEA, DIZZINESS.

First Aid:INHALATION: REMOVE TO FRESH AIR. INGESTION: NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. NEVER TRY TO MAKE AN
UNCONSCIOUS PERSON VOMIT. PRESS FINGERS TO BACK OF TONGUE TO INDUCE
VOMITING. OB TAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point:-20F
Lower Limits:1.6
Upper Limits:15.1
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:TOXIC VAPORS ARE FORMED WHEN MATERIAL IS
HEATED TO DECOMPOSITION (HYDROGEN CHLORIDE, HYDROGEN BROMIDE).

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.

Handling and Storage Precautions:MAY FORM EXPLOSIVE PEROXIDES DURING
STORAGE. REFRIGERATE IN SEALED CONTAINER. KEEP AWAY FROM OXIDIZERS
& IGNITION SOURCES.
Other Precautions:AVOID EYE/SKIN CONTACT & BREATHING VAPORS.

Respiratory Protection:WEAR NIOSH/OSHA APPROVED RESPIRATORY PROTECTION.
Ventilation:USE ONLY IN EXHAUST HOOD.
Protective Gloves:RECOMMENDED.
Eye Protection:PROTECTIVE GLASSES
Supplemental Safety and Health
THIS MATERIAL IS INTENDED FOR R&D USE ONLY & MAY NOT BE USED FOR DRUG,
HOUSEHOLD/OTHER PURPOSES. IT SHOULD BE HANDLED ONLY BY QUALIFIED
PERSONS TRAINED IN LABORATORY PROCEDURES & GOOD SAFETY PRACTICES .

Boiling Pt:B.P. Text:127.4F
Vapor Pres:201
Vapor Density:3.1
Spec Gravity:0.758
Appearance and Odor:CLEAR COLORLESS LIQUID

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OXIDIZING AGENTS.
Stability Condition to Avoid:IGNITION SOURCES.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, HYDROGEN BROMIDE.

Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.